All I can say is just WOW! The way that her hair falls on the side of Alessandra's face really brings out her eyes due to the way that the look contours her face. The curls bring this look some volume and life. You are going to want to cut your hair once every 4 weeks or so to ensure that those split ends stay away.
Makeup-wise, the sky is your limit when it comes to what will suit this look. Just make sure that you highlight your areas that show a lot in this look such as your nose and eye area, and contour the areas as well. Due to the openness of this look, you can wear glasses if you want which is always an added bonus.